Place the candy corn and peanut butter into a large microwave-safe bowl, and heat in the microwave in 30-second intervals, stirring well until it is fully melted and smooth.
Pour the mixture into a baking dish. Freeze for at least 20 minutes. Place the chocolate chips into a microwave-safe bowl, and heat in the microwave in 30-second intervals, stirring well until it is fully melted and smooth.
Cut the candy corn mixture into bars, and fully coat each candy bar into the melted chocolate. Set onto a large plate, and let sit until the chocolate has completely set.